Joshua Smith

Organometallic Aryne Chemistry

Attempts are being made to synthesize, and, perhaps, directly observe small aryns (e.g., benzyne) bound to the metals facially. These complexes are expected to open new routes to a new class of substituted aromatic metal complexes by reactions with nucleophiles and to allow novel entries into the synthesis of new and interesting bicyclic ring systems after trapping with dienes in situ.

Molecular Electronics